Contact and junction resistances in 2D semiconductors
Special Condensed Matter Seminar
Date
Friday, November 8, 2024 11:00 - 12:00
Speaker
Aleksandar Matkovic (Montanuniversitaet Leoben (Austria))
Location
Office Bldg West / Ground floor / Heinzel Seminar Room (I21.EG.101)
Series
Seminar/Talk
Tags
Physical Sciences Seminar
Host
Hryhoriy Polshyn
Contact
As the 2D materials based electronics develop towards very large-scale integrated circuits, one of the major challenges is to obtain high quality contact to 2D semiconductors. Carrier injection barriers, metal induced gap states, and consequently Fermi level pinning at the electrode interfaces hinder the integration of 2D semiconductors. Intrinsic properties of the channel 2D material are rarely accessible as usually majority of the bias intended for the carrier transport is used to overcome the contact related junctions. Further, in the case of polycrystalline films and assembled nanosheet networks also junctions between adjacent domains and nanosheets govern the macroscopic response of the devices.
This talk will focus on single crystalline MoS2, WSe2, PtSe2, and on liquid phase-exfoliated and liquid-liquid interface assembled MoS2 nanosheet networks. We will review several possible electrode choices, from organic self-assembled monolayers functionalized conventional metals, to van der Waals semi-metallic contacts. The focus will be on ways to evaluate contact related losses considering macroscopic electrical measurements, device modelling, and local probing of the electrostatic potential by in operando Kelvin Probe Force Microscopy. We will see how contact engineering can enhance the properties of 2D semiconductor devices, and also tailor carrier injection into 2D channels.
[1] Matkovi, A., et.al., Interfacial band engineering of MoS2/gold interfaces using pyrimidinecontaining selfassembled monolayers: toward contactresistancefree bottomcontacts. Advanced Electronic Materials 6, 2000110, 2020.
[2] Murastov, G., et.al., Multi-Layer Palladium Diselenide as a Contact Material for Two-Dimensional Tungsten Diselenide Field-Effect Transistors. Nanomaterials 14, 481, 2024.
[3] Gabbett, C., et.al., Understanding how junction resistances impact the conduction mechanism in nano-networks. Nature Communications 15, 4517, 2024.
[4] Aslam, M.A., et.al., All van der Waals Semiconducting PtSe2 Field Effect Transistors with Low Contact Resistance Graphite Electrodes. Nano Letters 24, 6529, 2024.