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TZID:Europe/Vienna
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DTSTART:20260329T030000
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DTSTART:20251026T020000
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BEGIN:VEVENT
DTSTAMP:20260424T143146Z
UID:68ff657c53a35945020073@ist.ac.at
DTSTART:20251112T110000
DTEND:20251112T120000
DESCRIPTION:Speaker: Maria Lukatskaya\nhosted by Stefan Freunberger\nAbstra
 ct: Electrolytes play a crucial role in energy storage devices\, impacting
  their environmental footprint\, safety\, cost\, and performance. This tal
 k will cover two key areas of electrolyte research for improving batteries
 .First\, we will explore water-based batteries. Aqueous electrolytes\, bei
 ng non-flammable and less toxic\, offer safer battery operation. However\,
  their limited electrochemical stability window reduces energy density. To
  address this\, highly concentrated "water-in-salt" (WIS) electrolytes hav
 e been developed\, significantly expanding the stability window and enhanc
 ing the performance of Li-ion and Zn metal batteries for grid energy stora
 ge. Despite their advantages\, WIS electrolytes have high viscosity and re
 quire large amounts of potentially toxic salts\, which limits their usabil
 ity. We will discuss how cation solvation\, electrolyte structure\, and hy
 drogen bonding influence the electrochemical properties and performance\, 
 particularly in Zn plating/stripping and electrolyte decomposition. Additi
 onally\, we will explore strategies for engineering relatively dilute elec
 trolytes for efficient aqueous batteries.Second\, the talk will present a 
 novel method for stabilizing interfaces in Li metal batteries (LiMBs). Con
 ventional electrolytes result in low cycle life and safety issues due to "
 dead" lithium and dendrite formation. Prior research suggests that fluorin
 e-rich interfacial layer chemistry is important for the stabilization of L
 i-metal anodes\, which can be achieved when electrolytes with a high fract
 ion of fluorinated solvents and/or salts are used. We propose an alternati
 ve approach using electrostatic attraction between positively charged read
 ily reducible fluorinated cations and the negatively charged anode. This m
 ethod enables the formation of a robust fluorine-rich interfacial layer wi
 th minimal additive (0.1 wt%)\, facilitating dense\, conformal Li depositi
 on. This strategy can offers a cost-effective\, environmentally friendly s
 olution for enhancing high-energy batteries.
LOCATION:Sunstone Bldg / Ground floor / Big Seminar Room B / 63 seats (I23.
 EG.102)\, ISTA
ORGANIZER:rpacarad@ist.ac.at
SUMMARY:Maria Lukatskaya: Engineering Local Chemical Environments in Electr
 olytes for Efficient Batteries
URL:https://talks-calendar.ista.ac.at/events/6119
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